Arsenal will face holders Barcelona in the Champions League last 16.
Roma versus Real Madrid and Juventus, last year’s beaten finalists, against Bayern Munich are two of the standout matches in the draw.
First legs are scheduled to take place on 16-17 and 23-24 February. Return legs are on 8-9 and 15-16 March.
The winners of each group, including Chelsea and Manchester City, are at home in the second legs, while Arsenal will host their first leg.
The draw for the quarter-finals will be held at 11:00 GMT on 18 March with the semi-final line-up drawn on 15 April, also at 12:00 GMT.
Gent v Wolfsburg
Roma v Real Madrid
Paris St-Germain v Chelsea
Arsenal v Barcelona
Juventus v Bayern Munich
PSV Eindhoven v Atletico Madrid
Benfica v Zenit St Petersburg
Dynamo Kiev v Manchester City